New class of thiocyanate-free cyclometalated ruthenium(II) complexes having a pyridylquinoline derivative for near-infrared sensitization of dye-sensitized solar cells

Abstract

A new class of thiocyanate-free cyclometalated ruthenium(II) complexes [Ru(dcpq) 2 (C^N)]Cl (where dcpq is 4-carboxy-2-(4′-carboxypyridin-2′-yl)quinoline and C^N is a bidentate cyclometalating ligand) ( FT22 and FT61 ) was synthesized as near-infrared (IR) sensitizers for dye-sensitized solar cells (DSSCs). Modification of the ligand improves photovoltaic performance, and DSSCs sensitized with FT61 show large photocurrents (> 21 mA cm − 2 ) as well as a 55% incident photon-to-current conversion efficiency (IPCE) at 800 nm and 25% IPCE at 900 nm. The complexes exhibit superior light-harvesting properties in the near-IR region. A new class of thiocyanate-free cyclometalated ruthenium(II) complexes was synthesized as near-IR sensitizers for DSSCs. FT61 -based cells show large photocurrents as well as a superior light-harvesting properties in the near-IR region. • We synthesize new thiocyanate-free Ru complexes as near-IR sensitizers for DSSCs. • Modification of the ligand improves the photovoltaic performance. • FT61-based cells exhibit J sc of 21.2 mA cm − 2 . • FT61 exhibits superior light-harvesting properties in the near-IR region. • DSSCs based on FT61 show 55% IPCE at 800 nm and 25% IPCE at 900 nm.