Abstract
Reactions of a low-valent cobalt complex [Co(nacnac)(η6-C7H8)] (1) ((nacnac)− = (HC(C(Me)NC6H3-iPr2)2)−) with selenium and tellurium are studied. Two new binuclear complexes [(Co(nacnac))2(μ,η2-Se2)] (2) and [(Co(nacnac))2(μ,η2-Te2)] (3) have been isolated and characterized. The structures of the complexes are determined by single crystal X-ray diffraction.
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