Abstract

New derivatives of dibenzo-18-crown-6 with carboxy groups in the side chain have been obtained by acylation with dibasic acids in the presence of polyphosphoric acid. Both 4′,4″- and 4′,5″-dicarboxydibenzo-18-crown-6's have been obtained by the oxidation of the corresponding diacetyl derivatives and have been separated into the isomers. The 4′,4″- and 4′,5″-diformyldibenzo-18-crown-6's have been obtained by the reaction of dibenzo-18-crown-6 with hexamethylenetetramine in polyphosphoric acid.

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