Abstract
New binucleating ligands containing μ-alkoxo backbones and amido-pyridyl or amido-phenol “end” groups have been synthesized. The syntheses and structures of mononuclear Cu II and binuclear (Cu IICu II and Mn IIIMn III) complexes are described. The crystal structure of a novel doubly-bridged Mn IIIMn III complex shows that each six-coordinate manganese is bridged by endogenous μ-alkoxo and exogenous μ-acetato groups. Chemical or electrochemical oxidations will be required to obtain higher oxidation state metallo species.
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