Abstract

Abstract The mechanism of nucleophilic opening of epoxide rings has been investigated by studying the kinetics of (i) amine-epoxide reactions both in the absence and presence of hydroxyl-containing catalysts, (ii) reactions of commercial epoxydiane oligomers of different molecular weights with aromatic diamines ( m -phenylene diamine), and (iii) reactions of epoxides with phenols in the absence and presence of alkali.

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