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Abstract
A new approach to determining each component of a two-component overlapping peak in single-column anion ion chromatography analysis is described. In single-column anion ion chromatography analysis, if the sample is the same as the eluent, the sample peak will not appear. If the sample is not the same as the eluent and the limiting equivalent conductance of the sample is different from that of the eluent, the sample peak will appear. Therefore, one component of a two-component overlapping peak can be determined with the other component as eluent. The method was tested by the overlapping peak of molybdate and tungstate and of tartaric and citric acids. A minor rearrangement of the detection equation for ion chromatography is also described in this paper.
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