Abstract
AbstractA new approach for the synthesis of well‐defined poly(aminoethyl vinyl ether)s with controllable molecular weight has been developed. In a first step poly(chloroethyl vinyl ether)s with narrow molecular weight were prepared via living cationic polymerization of chloroethyl vinyl ether with 1,1‐diethoxyethane/trimethylsilyl iodide/zinc iodide as initiating system. The chloro groups of the resulting polymers were subsequently substituted into phthalimide groups, resulting in the formation of poly(phthalimide ethyl vinyl ether). Hydrazinolysis of the imide functions gave rise to the desired poly(aminoethyl vinyl ether)s. The polymers were characterized by 1H NMR, size exclusion chromatography and X‐ray spectroscopy. The resulting polyamine was soluble only in water and in methanol and showed polyelectrolyte behaviour, as revealed by viscosimetry studies. Copyright © 2003 Society of Chemical Industry
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
