Abstract

N-benzoyl-2-methylalanines , obtained through condensation of aroyl chlorides with sodium 2-methylalaninate are ortho-hydroxylated by the nex Cu(0)/O 2 /trimethylamine N-oxide system. Acid hydrolysis of the so-obtained salicylamides provides salicylic acids in excellent yield. When the substrate contains three electron-releasing groups the yields are moderate

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