Abstract
In this work, a new analysis of the transition Ã2Πu→X̃2Πg of the CO2+ molecule was carried out by Fourier Transform spectroscopy. More accurate wavenumbers allowed the improvement of molecular constants and band origins, leading to more reliable values for molecular parameters. Particularly in the first three vibrational levels v1′00 of symmetric stretching, as well as in the vibrational levels 010 and 110, in the excited electronic state Ã2Πu. Combining with previously reported data, it was possible to calculate, for the first time, a complete set of Renner–Teller parameters for the ground electronic state X̃2Πg.
Published Version
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