Abstract

AbstractA new series of relatively stable adducts of octahydro‐1,3,5,7‐tetranitro‐1,3,5,7‐tetrazocine (HMX) with derivatives of pyridine‐N‐oxide were prepared. In addition, relative stable new adducts of HMX were prepared with 5‐membered, 6‐membered, and condensed‐ring heterocyclic compounds. Most of the adduct‐forming compounds (AFC's) contain an oxygen and/or nitrogen heteroatom, while several contain a sulfur heteroatom. Most of the adducts are equimolar with HMX; however, several contain 2 moles of AFC per mole of HMX and other ratios of AFC:HMX. Some properties of the new adducts are presented.

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