Abstract
AbstractPolythiocarbamyl sulfenamides were synthesized by the reaction of different aliphatic and aromatic diamines with carbon disulfide and using iodine as oxidant. The polymerization proceeds by radical mechanism. All the polymers are soluble in polar solvents like N‐methylpyrrolidone (NMP), dimethylformamide (DMF), m‐cresol etc. The structure of the polymers was confirmed by elemental analysis (nitrogen and sulfur), IR, and 1H‐NMR spectral analysis. The effects of aliphatic and aromatic moieties in the diamines were reflected in their reactivities.
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