Abstract
The structure of a hydrogel consisting of diamond nanoparticles formed by the explosion method has been studied. Small angle neutron scattering has been used as a method for characterization of the gel. Joint approaches for data analysis in reciprocal and direct space have been developed to restore a multilevel structure. The pristine hydrogel of positively charged diamond particles (~5 nm in size, concentration ~5 wt %), even by four-fold dilution below its formation critical point, (C* ~ 4 wt %) retains practically the original structure where single particles are joined into small groups integrated into chain fractal-type aggregates creating a network. This indicates a local stability of the gel and means a transformation of continuous gel into a system of micro-domains suspended in water. A perfection of the diamond crystals’ facets was revealed that is of principal importance for the configuration of potentials, inducing the diamonds’ electrostatic attraction due to different electric charges of facets. It is distinguished from the results for the suspensions of diamonds in graphene shells that showed a deviation of scattering from Porod’s law.
Highlights
The detonation synthesis of diamonds [1,2,3] is associated with a problem of their removal from aggregated carbon products, because milling yields the damaged diamonds with graphene-like coatings [4,5]
The structure of a hydrogel consisting of diamond nanoparticles formed by the explosion method has been studied
Small angle neutron scattering has been used as a method for characterization of the gel
Summary
The detonation synthesis of diamonds [1,2,3] is associated with a problem of their removal from aggregated carbon products, because milling yields the damaged diamonds with graphene-like coatings [4,5]. In previous papers [11,12,13] devoted to the studies of diamonds’ suspensions, the analysis was based mainly on modeling the q-dependencies of scattering intensities (cross sections) by some fractal laws which described the data in the corresponding intervals of momentum transfers. This approach gives a set of structural parameters resulting from the analysis in the frameworks of the chosen models. In our work we have applied the formalism of correlation functions to restore in detail the specific features of particles’ arrangements to find the characteristics of their self-assembly in hydrogels where different structural levels exist
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