Abstract
AbstractNeutron inelastic scattering spectra of HC1, CH3Cl, CH3CN, and CH3I isolated in matrices of solid argon and sulphur hexafluoride at energy transfers of 0–300 cm−1 are reported. Only HCl shows rotation, whereas the spectra of the other compounds are due to liberational modes of the methyl group about the figure axis. In argon, all modes are strongly damped by the phonons of the matrix.
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