Abstract

A high-resolution neutron powder diffraction study of the fluorite structured compound β-PbF 2 has been performed at ∼100 different temperatures in the range 273–1078 K. Rietveld profile refinement of the data confirms the presence of an anomaly in the thermal expansion coefficient at temperatures close to the fast-ion transition ( T c≈711 K) and gives detailed information concerning the extent of anion disorder within the fast-ion phase.

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