Neutron Diffraction Study of the Structures of Ba5CuIr3O12 and Ba16Cu3Ir10O39

Abstract

The crystal structures of Ba{sub 5}CuIr{sub 32}O{sub 12} and Ba{sub 16}Cu{sub 3}Ir{sub 10}O{sub 39} have been determined using a combination of X-ray and neutron powder diffraction data. Considering their structures to be based on hcp stacks of Ba{sub 2}O{sub 9} and Ba{sub 3}CuO{sub 6} layers, Ba{sub 5}CuIr{sub 3}O{sub 12} has a 10-layer structure. Ba{sub 16}Cu{sub 3}Ir{sub 10}O{sub 39} has a 16-layer structure. Sequences of trigonal prismatic and octahedral transition metal sites run in chains parallel to z, with Ba cations located between the chains. The distribution of Ir and Cu cations in the octahedral and trigonal prismatic sites is disordered in both compounds. Cu cations are displaced from the centers of the trigonal prisms toward the rectangular faces. Both materials may also be regarded as commensurate composites of two substructures, sharing common unit cell parameters a and b but with different parameters c{sub 1} and c{sub 2}, where the ratio c{sub 1}/c{sub 2} is a rational fraction. The relative merits of the oxide layer model and the composite crystal model are discussed.