Neutron diffraction study of La 4LiAuO 8: Understanding Au 3+ in an oxide environment

Abstract

Owing to gold's oxophobicity, its oxide chemistry is rather limited, and elevated oxygen pressures are usually required to prepare ternary and quaternary oxide compounds with gold ions. The Au 3+ oxide, La 4LiAuO 8, is remarkable both because it can be prepared at ambient pressure in air, and because of its unusual stability toward thermal decomposition and reduction. The structure of La 4LiAuO 8 was established by Pietzuch et al. using single crystal X-ray diffraction [1]. The compound adopts an ordered modification of the Nd 2CuO 4 structure, containing two-dimensional sheets in which AuO 4 square planes are separated from one another by LiO 4 square planes. In light of the meager X-ray scattering factors of Li and O, relative to La and Au, we report here a neutron powder diffraction study of La 4LiAuO 8, definitively confirming the structure. To our knowledge, this is the first reported neutron diffraction study of any stoichiometric oxide compound of gold. X– N maps, which make use of nuclear positions obtained from Rietveld refinement of time-of-flight neutron diffraction data and electron densities obtained from synchrotron X-ray powder diffraction data, point to the highly covalent nature of the Au–O bonding in La 4LiAuO 8. This is in good agreement with charge densities and Bader charges obtained from full density functional relaxation of the structure.