Abstract

Temperature dependent neutron powder diffraction has been used to study the β″ Na(H2O, H3O+) ferrite compound from room temperature to 830°C. The following phenomena were observed: 1.(i) The existence of two superimposed magnetic modes, one ferromagnetic described with the propagation vector k = [0 0 0], the other one antiferromagnetic which is described with the propagation vector k = [0 032]. The antiferromagnetic (AF) model arrangement is in fact an extrapolation of Gorter's (AF) collinear model proposed for the potassium β-ferrite. The two magnetic modes are in agreement with the representation theory analysis.2.(ii) The existence of two transitions one at T = 250°C (of magnetic origin), the other one (of nuclear or magnetic origin) at T = 450°C.3.(iii) From the variation of cell parameters with temperature there is evidence of the complete desorption of water at T = 220°C.

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