Abstract

Neutron diffraction of a single crystal and of powder samples of composition Mn 0.88Fe 0.12WO 4 were performed to study the magnetic structure. A commensurate antiferromagnetic (AF) structure with the wavevector k=(0.25 0.5 0.5) between 1.5 and 13.5 K and an incommensurate AF structure with k=(0.23 0.5 0.508) were determined. A magnetic phase similar to that of FeWO 4 is observed between 19 and 13.3 K. Below 13.3 K magnetic diffraction intensities indexed to the magnetic unit cell of FeWO 4 are still present, however, cannot be related to the FeWO 4-type structure alone.

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