Neutron activation analysis of sediments of the Padma River adjacent to Rooppur Nuclear Power Plant: Elemental and multivariate statistical approach

Abstract

This study investigated the major and trace element concentrations in the sediments of the Padma River adjacent to the under-construction Rooppur Nuclear Power Plant to have baseline elemental concentration data. Instrumental Neutron Activation Analysis (INAA) was used to determine a total of twenty-three elements (Al, As, Ca, Ce, Co, Cr, Cs, Dy, Eu, Fe, Hf, La, Mn, Na, Sb, Sc, Sm, Ti, Th, U, V, Yb, and Zn). The calculation of the enrichment factor, geo-accumulation index, and pollution load index revealed that most of the sediment samples were minor to moderately contaminated by twelve elements (As, Ca, Ce, Cs, Dy, Hf, La, Sb, Sm, Th, U, and Yb). An ecological risk assessment by ecological risk factor, comprehensive potential ecological risk index, and sediment quality guidelines showed that the sampling locations were subject to harmful biological effects due to high concentrations of As and Cr in the sediments. Three multivariate statistical analyses identified two groups of elements based on their characteristics in the sediments. This study will act as baseline elemental concentration data for future studies concerning anthropogenic activities in this area.