Abstract
In the present work we report a spectroscopic investigation of the pressure-induced neutral to ionic (NI) phase transition in the mixed stack charge-transfer crystal 2-chloro-5-methyl-p-phenylenediamine 2,5-dimethyl-dicyanoquinonediimine, ClMePD-DMeDCNQI. The pressure induced phase change is studied by calculating, from spectroscopic data, the degree of ionicity, 𝜌 , which undergoes a continuous change as a function of pressure, reaching a value of about 0.65 at 3 GPa. The NI crossing reveals unique properties with respect to previously studied cases on similar compounds.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
