Neutral saccharides and hemicellulose over two urban sites in Indo-Gangetic Plain and Central Europe during winter

Abstract

Saccharides are ubiquitous organic compounds that are omnipresent in nature and are considered tracers of aerosol sources. Saccharides and hemicellulose were analyzed in the aerosols of two polluted regions (Allahabad, India and Sosnowiec, Poland). The chemical compositions of the compounds and their abundances were significantly different at the two sites. Levoglucosan was the most dominant saccharide present at both sites. Galactosan, anhydroglucofuranose, mannosan, glucose, arabitol, D-pinitol, sucrose, and trehalose were found in Allahabad samples in high abundance but were significantly lower than levoglucosan. Mannosan, galactosan, arabinose, glycerol, and sucrose were significant compounds in Sosnowiec after dominating levoglucosan. The major sources of saccharides present in the Allahabad aerosols are hardwood and agricultural waste-burning emissions, whereas those at Sosnowiec are attributed to the burning of softwood (mainly gymnosperm trees), pine needles, or sporadically grass during the winter. Further, the chemical characteristics of hemicellulose remnants present in ambient aerosol at the Indian and European sites were analyzed and discussed. At both locations, hemicellulose was found using methanolysis of the filter samples; however, its state of preservation was poor. We believe that the primary sources of hemicellulose remnants are incomplete wood burning, crop straw, grass burning, or plant debris. Relatively poor preservation is associated with partial hemicellulose degradation when exposed to elevated temperatures or due to the oxidation and microbial degradation of plant fragments.