Abstract
New Trinuclear Rhenium Complexes with Bridging Nitrido Ligands Trinuclear complexes with bridging nitrido ligands between the rhenium atoms are formed when [ReN(Et2dtc)2 · (Me2PhP)] (Et2dtc– = N,N-diethyldithiocarbamate) reacts with TlCl or Pr(O3SCF3)3. [Cl(Me2PhP)2(Et2dtc)Re≡N–Re(N) · Cl2(Me2PhP)–N≡Re(Et2dtc)(Me2PhP)2Cl] and [(Et2dtc)2 · (Me2PhP)Re≡N–Re(N)(Et2dtc)(Me2PhP)–N≡Re(Me2PhP) · (Et2dtc)2]+ contain two almost linear, asymmetric nitrido bridges. Additional, terminal nitrido ligands are located at the middle rhenium atoms.
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