Abstract

In spite of their synthetic use in organic chemistry, only a few alkynyl derivatives of group 13 metals are known in the literature and a very few of them are structurally characterized.In this dissertation there are reported the first ionic aluminum/ gallium/ indium compounds carrying three terminal ethynyl groups which show interesting structural properties.In the continuing research the first neutral halogeno compounds of Al, Ga and In with two ethynyl moieties connected to the metal were synthesized.Additionally it is described the preparation of the first exclusively N-based tetrameric Al(I)-compound.

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