Neoteric approach for efficient eco-friendly dye removal and recovery using algal-polymer biosorbent sheets: Characterization, factorial design, equilibrium and kinetics

Abstract

A new approach of algal-polymer -sheets was performed by the embedding of two algal seaweeds (Ulva fasciata and Sargassum dentifolium) into cellulose acetate (CA) polymer forming two types of cellulose acetate; Ulva (CA-U) and Sargassum (CA-S) sheets. Afterward, the two sheets were characterized then subjected to 3-Rs evaluation (Removal, Recovery, and Reuse) of methylene blue dye (MB). Characterization data exhibited good properties for biosorption process. Algal biosorbents achieved more than twice biosorption capacity (Qmax) after the embedding into the polymer sheet. Additionally, according to factorial design data, the contact time and the dose of biosorbents had positive effects on the biosorption in the two sheets. Freundlich, Langmuir, and pseudo-second order models displayed good represented data in the two sheets. Furthermore, the two sheets (CA-U, followed by CA-S sheet) were successfully given more than 98% adsorption of 273 mg/l MB concentration. Moreover, the recovery and reuse data proved that the two sheets can be performed in good behavior for more than three cycles.