Neoproterozoic non-glaciogenic iron formation: Insights from Fe isotope and elemental geochemistry of the Shalong iron formation from the Central Tianshan block, southern Altaids

Abstract

The return of widespread banded iron formation (BIF) deposition during the Neoproterozoic Era after a more than one-billion-year hiatus appears to be a hallmark of the Neoproterozoic, and may be indicative of critical changes in the Earth’s environmental and tectonic conditions. However, consensus on the Fe sources and origin of Neoproterozoic iron formations (NIFs) remains elusive. Here we present new petrographic and geochemical data from the newly discovered Shalong NIF from the Central Tianshan block in order to constrain the iron source and elucidate the origin and depositional conditions of the NIF. The major and trace element composition of the Shalong NIF indicates that it is a relatively pure chemical sediment with a low detrital input. Rare earth elements and Y patterns (REY) exhibit seawater-like signature such as depletion in light REEs (LREEs) and enrichment in heavy REEs (HREEs). The weak positive Eu anomalies (Eu/Eu∗ = 1.11–1.31) and consistent chondritic Y/Ho ratios of 25 to 29 (average 26) suggest a predominant influx of low-temperature hydrothermal fluids. The geochemistry of the Shalong NIF also supports a predominant hydrothermal iron source characterized by low-temperature hydrothermal fluids. The lack of negative Ce anomalies, as well as weak positive Eu anomalies, and positive and variable δ56Fe values (−0.09‰ to +1.28‰) in the Shalong NIF indicates partial Fe2+ oxidation in a relatively large dissolved iron marine basin under oxygen-limited conditions. The Shalong NIF deposition likely took place on the slope of an extensional oceanic basin in a low energy environment. The Shalong NIF has a close association with metamorphized- bimodal volcanic rocks and predominant hydrothermal iron source. Combined with no sign for any glacial influence and depositional age prior to the global Sturtian glaciations, we suggest that the Shalong NIF is a non-glaciogenic Neoproterozoic iron formation in association with volcanic and hydrothermal activity. Our results, in conjunction with previous studies, suggest that glacial events are not essential or necessary for the origin of all the NIFs. Instead, hydrothermal activity seems to be a more important controlling factor for the build-up of ferruginous basins and subsequent iron oxidation events in the Neoproterozoic leading to the sudden recurrence of NIFs.