Neoproterozoic metasomatized mantle beneath the western Yangtze Block, South China: Evidence from whole-rock geochemistry and zircon U-Pb-Hf isotopes of mafic rocks

Abstract

Mafic rocks contain important information about the nature of the mantle source and tectonic settings. Here we present results of whole-rock geochemistry and zircon U-Pb-Hf isotopes for the Early Neoproterozoic mafic rocks (Ganyuhe hornblende gabbros and Guandaoshan gabbro-diorites) in the western Yangtze Block, South China, in order to constrain the petrogenesis and the mantle metasomatism processes under subduction setting. LA-ICP-MS zircon U-Pb dating results display concordant crystallization ages of 857.4 ± 2.0 Ma for the hornblende gabbros and 856.4 ± 2.8 Ma for the gabbro-diorites, respectively. These mafic rocks possess low SiO2 contents (45.5–53.3 wt%) as well as high MgO contents (3.27–9.20 wt%) and Mg# (48.6–62.6) values, and show characteristics of arc-like trace element patterns with enriched Rb, Ba, Sr, K, and Pb but depleted Nb, Ta, Zr, Hf, and Ti. The prominently positive whole-rock εNd(t) (+4.9 to + 5.8) and zircon εHf(t) (+8.48 to + 20.6) values suggest a depleted lithospheric mantle source. We therefore infer that the mafic rocks investigated here were derived from an amphibole-bearing spinel peridotite source that was affected by metasomatism between the overlying mantle wedge and subduction-related fluids. In conjunction with the compiled data of Neoproterozoic mafic rocks from the western Yangtze Block, we propose that there exist Neoproterozoic metasomatized mantle sources beneath the western Yangtze Block during the subduction process in response to the evolution of the supercontinent Rodinia. The Neoproterozoic metasomatic agents in mantle sources include the slab fluids, sediment melts, and oceanic slab melts.