Abstract
The solid neon matrix isolated spectrum of CO 2 are recorded in the 2–5 μm region. Natural and 13C or 18O enriched CO 2 samples were used and the nν 1 + ν 3 ( n = 0, 1, 2) series bands of different CO 2 isotopologues have been observed. The solid neon matrix shift due to Fermi-resonance of bands within the same vibrational polyad is analyzed.
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