Abstract

AbstractA novel metal‐free intramolecular Brønsted‐acid‐catalyzed domino deprotection–hydrosilylation with hydrosilanes has been developed, and the unexpected Brønsted‐acid‐catalyzed intermolecular hydrolytic oxidation to functional siloxanes was described for the divergent and facile synthesis of functionalized siloxanes containing aldehyde motifs. We propose that these reactions proceed via neighboring acetal‐assisted Si–H bond activation. In addition, a related reaction is expected to open up further opportunities for the development and application of functional organosilicon compounds by organocatalysis.

Full Text
Paper version not known

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call

Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.