Neighborhood-Level Nitrogen Dioxide Inequalities Contribute to Surface Ozone Variability in Houston, Texas.

Abstract

In Houston, Texas, nitrogen dioxide (NO2) air pollution disproportionately affects Black, Latinx, and Asian communities, and high ozone (O3) days are frequent. There is limited knowledge of how NO2 inequalities vary in urban air quality contexts, in part from the lack of time-varying neighborhood-level NO2 measurements. First, we demonstrate that daily TROPOspheric Monitoring Instrument (TROPOMI) NO2 tropospheric vertical column densities (TVCDs) resolve a major portion of census tract-scale NO2 inequalities in Houston, comparing NO2 inequalities based on TROPOMI TVCDs and spatiotemporally coincident airborne remote sensing (250 m × 560 m) from the NASA TRacking Aerosol Convection ExpeRiment-Air Quality (TRACER-AQ). We further evaluate the application of daily TROPOMI TVCDs to census tract-scale NO2 inequalities (May 2018-November 2022). This includes explaining differences between mean daily NO2 inequalities and those based on TVCDs oversampled to 0.01° × 0.01° and showing daily NO2 column-surface relationships weaken as a function of observation separation distance. Second, census tract-scale NO2 inequalities, city-wide high O3, and mesoscale airflows are found to covary using principal component and cluster analysis. A generalized additive model of O3 mixing ratios versus NO2 inequalities reproduces established nonlinear relationships between O3 production and NO2 concentrations, providing observational evidence that neighborhood-level NO2 inequalities and O3 are coupled. Consequently, emissions controls specifically in Black, Latinx, and Asian communities will have co-benefits, reducing both NO2 disparities and high O3 days city wide.