Negative sulfur-based electrodes and their application in battery cells: Dual-ion batteries as an example

Abstract

In this work, a cell concept comprising of an anion intercalating graphite-based positive electrode (cathode) and an elemental sulfur-based negative electrode (anode) is presented as a transition metal- and in a specific concept even Li-free cell setup using a Li-ion containing electrolyte or a Mg-ion containing electrolyte. The cell achieves discharge capacities of up to 37 mAh g−1 and average discharge cell voltages of up to 1.9 V. With this setup, more than 100 cycles with a high capacity retention (> 90% of the highest achieved value) and Coulombic efficiencies up to 95% could be achieved, which opens a broad new field for energy storage approaches.