Abstract
AbstractThe gas‐phase negative‐ion chemistry of 2‐methylpropenal has been studied by Fourier transform ion cyclotron resonance mass spectrometry (FT‐ICR). Deuterium labelling has shown that the gas‐phase acidities of the methyl protons and the formyl proton are almost equal. The gas‐phase reactions of the 2‐formylallyl anion with several fluorinated substrates have been shown to proceed mainly via a cycloaddition mechanism.
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