Nearly complete isobar suppression by photodetachment

Abstract

The efficiency of selective suppression of negative ions by photodetachment in a gas-filled radio frequency quadrupole ion cooler was investigated with a new detection method. A neodymium doped yttrium aluminum garnet laser beam at 1064 nm was used to remove Co− ions in the radio frequency quadrupole cooler and the remaining ions were then probed by photodetachment and neutral particle detection. More than 99.99% suppression of the Co− ions was observed. Under identical conditions, only 20% of a Ni− beam was suppressed. The results demonstrate that this isobar suppression technique can lead to nearly complete elimination of certain isobaric contaminants in negative ion beams, opening up new experimental possibilities in nuclear and atomic research and accelerator mass spectrometry.