Abstract

The A ̃ 3 Π i(000) ← X ̃ 3 Σ −(000) band of the CCO radical has been reinvestigated by means of near-infrared high-resolution diode laser spectroscopy in the region from 11 607 to 11 731 cm −1 with Doppler-limited resolution. The spectrum has been analyzed to obtain detailed molecular constants for the A ̃ 3 Π i(000) state including Λ-type doubling constants. Numerous perturbations have been found in the Ω = 0 and 1 levels of the A ̃ 3 Π i(000) state in the present study.

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