Abstract

The behavior of the detonation velocity near the limits is investigated. Circular tubes of diameters 65, 44 and 13mm are used. To simulate a quasi two-dimensional rectangular geometry thin annular channels are also used. The annular channels are formed by a 1.5m long insert of a smaller diameter tube into the larger outer diameter detonation tube. Premixed mixtures of C2H2+2.5O2+70%Ar, CH4+2O2 and C2H2+5N2O+50%Ar are used in the present study. The high argon dilution stoichiometric C2H2+2.5O2 mixture has a regular cell size and piecewise laminar reaction zone and thus referred to as “stable”. The other two mixtures give highly irregular cell pattern and a turbulent reaction zone and are hence, referred to as “unstable” mixtures. Pressure transducers and optical fibers spaced 10cm apart along the tube are used for pressure and velocity measurements. Cell size of the three mixtures studied is also determined using smoked foils in both the circular tubes and annular channels. The ratio d/λ (representing the number of cells across the tube diameter) is found to be an appropriate sensitivity parameter to characterize the mixture. The present results indicate that well within the limit, the detonation velocity is generally a few percent below the theoretical Chapman–Jouguet (CJ) value. As the limit is approached, the velocity decreases rapidly to a minimum value before the detonation fails. The narrow range of values of d/λ of the mixture where the velocity drops rapidly is found to correspond to the range of values for the onset of single headed spinning detonations. Thus we may conclude that the onset of single headed spin can be used as a criterion for defining the limits. Spinning detonations are also observed near the limits in annular channels.

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