Abstract
Herein, two new quadrupolar acceptor-π-donor-π-acceptor (A-π-D-π-A) chromophores have been prepared featuring a strongly electron-donating diborene core and strongly electron-accepting dimesitylboryl (BMes2 ) and bis(2,4,6-tris(trifluoromethyl)phenyl)boryl (BF Mes2 ) end groups. Analysis of the compounds by NMR spectroscopy, X-ray crystallography, cyclic voltammetry, and UV/Vis-NIR absorption and emission spectroscopy indicated that the compounds have extended conjugated π-systems spanning their B4 C8 cores. The combination of exceptionally potent π-donor (diborene) and π-acceptor (diarylboryl) groups, both based on trigonal boron, leads to very small HOMO-LUMO gaps, resulting in strong absorption in the near-IR region with maxima in THF at 840 and 1092 nm and very high extinction coefficients of ca. 120 000 m-1 cm-1 . Both molecules also display weak near-IR fluorescence with small Stokes shifts.
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