Near-Infrared Laser Direct Writing of Conductive Patterns on the Surface of Carbon Nanotube Polymer Nanocomposites.

Abstract

Near-infrared (NIR) laser annealing is used to write conductive patterns on the surface of polypropylene/multi-walled carbon nanotube nanocomposite (PP/MWCNT) plates. Before irradiation, the surface of the nanocomposite is not conductive due to the partial alignment of the MWCNT, which occurs during injection molding. We observe a significant decrease in the surface sheet resistance using NIR laser irradiation, which we explain by a randomization of the orientation of MWCNTs in the PP matrix melt by NIR laser irradiation. After only 5 s of irradiation, the sheet resistance of PP/MWCNTs, annealed with a laser at a power density of 7 W/cm2, decreases by more than 4 decades from ∼100 MΩ/sq to ∼1 kΩ/sq. Polarized Raman, TEM, and SEM are used to investigate the changes in the sheet resistance and confirm the physico-chemical processes involved. This allows direct writing of conductive patterns using a NIR laser on the surface of nanocomposite polymer substrates, with the advantages of a fast, easy, and low-energy consumption process.