Near-infrared Fourier transform Raman spectroscopy: Facing absorption and background

Abstract

Visible wavelength excitation enables Raman spectra to be recorded successfully from approximately 10% of the “real, live” samples encountered in routine analytics without recourse to purification procedures. Fluorescence from impurities present in the sample often masks the Raman spectrum. This is especially true of the industrial environment. The great advantage of the newly-developed technique of near-infrared Fourier transform Raman spectroscopy (NIR FTR) is that fluorescence arising from sample impurity is not excited. Now about 90% of all samples show Raman spectra. However, it is possible to increase both the number of samples open to study using NIR FTR and to improve the quality of the spectra by optimizing the sampling arrangement. This involves taking into consideration the optical properties of the sample, especially the absorption spectrum and thermal emission characteristics, according to Planck's and Kirchhoff's laws. Only a few samples continue to show continuous backgrounds; this is sometimes true even if no background is apparent with visible excitation. The sources of such backgrounds are described, as are means to reduce or eliminate most of them.