Abstract

Photoluminescence spectra in Sb2S3 have been investigated for the first time. The photoluminescence composed of many peaks is observed near the indirect fundamental gap at 2 K. From the study of sample, excitation intensity and temperature dependences of photoluminescence and the time decay spectra, it is shown that the photoluminescence is caused by three different origins. Models of the origins are proposed. It is also shown that the photoluminescence spectra are very sensitive to the deviation from stoichiometry.

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