Abstract

A study of the optical properties of Nd3+ ion in TeO2–PbF2–AlF3 glasses has been carried out for different Nd3+ concentrations. Based on the Judd–Ofelt theory, intensity parameters and radiative properties were determined from the absorption spectra. Focusing on the suitability of this host for laser applications, the spectroscopic quality factor χ was obtained with a value of 1.07, a value of the order of other compositions proposed as laser hosts. For the most intense emission corresponding with the 4F3/2→4I11/2 transition (1.06μm), the absorption and emission and have been calculated with values of 1.20×10−20cm2, 2.08×10−20cm2. A positive value for the gain cross-sections has been found for a population inversion factor γ of 0.4 in the spectral range from 1060 to 1110nm. All these results suggest the potentially use of this system as a laser host.

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