Nd³⁺-Yb³⁺ doped powder for near-infrared optical temperature sensing.

Abstract

Er³⁺ doped powders are generally used for fluorescence-based temperature sensing application when near-infrared lasers are the excitation sources of choice. The fluorescence of Er³⁺ is produced by nonlinear (upconversion) processes, which generate strong internal heat. Lowering the excitation power causes drastic reduction of the fluorescence signal, and as a consequence the sensor applicability of Er³⁺ doped powders becomes compromised. Here we propose the use of the downconverted fluorescence of Yb³⁺ produced by efficient energy transfer from Nd³⁺ as an alternative temperature sensing system. Our results are presented for yttrium silicate powders prepared by combustion synthesis.