Abstract

Summary of main observation and conclusionA series of NCP‐type pincer iridium complexes, (RNCCP)IrHCl (2a—2c) and (BQ‐NCOP)IrHCl 3, have been studied for catalytic transfer alkane dehydrogenation. Complex 3 containing a rigid benzoquinoline backbone exhibits high activity and robustness in dehydrogenation of alkanes to form alkenes. Even more importantly, this catalyst system was also highly effective in the dehydrogenation of a wide range of heterocycles to furnish heteroarenes.

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