Abstract
The nature of the reentrant demixing transition in binary solutions with H bonds is studied in the framework of an Ising-like Hamiltonian with effective spin-spin interaction constant. It is taken into account that the internal variables describing the H-bond network are characterized by the spatial time scales essentially shorter than those for the spin variables. Due to this the contribution of H bonds to the effective spin-spin interaction constant is described by thermodynamic methods. With the help of the catastrophe theory the classification of possible types of phase diagrams leading to the double critical point is given. The influence of small quantities of third component (electrolytes, water, and molecules similar to CCl4) is discussed.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
