Nature and Isomorphism of Extra-Framework Components in Cancrinite- and Sodalite-Related Minerals: New Data

Abstract

New data on the isomorphism of extra-framework components (including chromophores) in two- and multilayer minerals belonging to the cancrinite and sodalite groups, are obtained using chemical and single-crystal X-ray diffraction data as well as infrared, Raman, ESR, UV–Vis–near IR absorption and photoluminescence spectroscopy methods. It is shown that the blue color of these minerals may be due to CO3•− or S3•− radical anions, whereas yellow and pink shadings are typically due to the presence of S2•− radical anions and S4•− or S4, respectively. Two kyanoxalite varieties are distinguished: (1) with predominantly acid oxalate groups and (2) predominantly neutral oxalate groups. Zundel cation H5O2+ and CO2 molecules are shown to be typical impurities in nosean. The Zundel cation is also detected in kyanoxalite and in the 12-layer, cancrinite-related mineral marinellite. Wide isomorphic series involving substitutions of SO4− for SO32− and CO32−, as well as OH− for H2O and F−, are common for eight-layer, cancrinite-group minerals with an afghanite-type framework.