NATURE AND DISTRIBUTION OF SECONDARY SOIL CARBONATES WITHIN LANDSCAPES IN RELATION TO SOLUBLE Mg++/Ca++ RATIOS

Abstract

The presence of magnesium-bearing calcites in secondary carbonate accumulation layers of soils is shown to be associated with soluble Mg++/Ca++ ratios of one or greater in the attendant or underlying layers. The dissolution of both calcite and dolomite within the solum and the precipitation of only calcite in the developing Cca leads to a buildup of Mg++ in the soil solution. If leaching depth is considerably below the Cca horizon, the secondary calcite is Mg free. If leaching is restricted to relatively shallow depths (2–4 m), the buildup of soluble salts and the increased soluble Mg++/Ca++ ratio which result are conducive to the precipitation of Mg-bearing calcites. Soluble salt distribution within a glacial till landscape suggests that surface runoff waters and snow accumulation in depressions are more important aspects of water distribution in such landscapes than is lateral movement within the soil itself. The accumulation of soluble salts in the 2 to 4-m zone of upland soils and the complete lack of salts to greater depths in depressions ties in well with the presence or absence of Mg-bearing calcites. The implications of the nature of the carbonates to soil salinization processes are indicated.