Abstract
43Ca MAS NMR spectra have been collected for 12 solid phases including silicates, carbonates and sulphates. In all cases 43Ca was present at natural abundance, the first time such experiments have been reported. In general the lines are broad and featureless, though in the case of calcite a second order quadrupolar lineshape was observed. Within each class of compounds (silicates, carbonates etc.), the isotropic chemical shift appears to be linearly correlated with the mean CaO bond length of the first coordination shell of calcium, with a similar gradient for all of the classes of compounds studied.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
