NaSrVO4:Sm3+ − An n-UV convertible phosphor to fill the quantum efficiency gap for LED applications

Abstract

The structural and luminescent properties of Sm3+ doped NaSrVO4 phosphors prepared by the combustion method were investigated. The phosphors were characterized by powder X-ray diffraction (XRD), transmission electron microscopy (TEM), photoluminescence spectroscopy (PL) and diffuse reflectance spectroscopy (DRS). NaSrVO4 crystallized into the monoclinic phase with P21/n space group. The Debye Scherrer׳s formula and Williamson–Hall (W–H) plot were used to determine the average crystallite size of the phosphors. Upon near-UV excitation, the phosphor gives the characteristic orange–red emission ascribed to the intra-4f-shell 4G5/2 to 6HJ (J=5/2, 7/2, 9/2, 11/2) transitions of Sm3+. The diffused reflectance spectra of the phosphors were used to calculate the optical band gap (Eg) of the material, which was estimated to be 3.58eV. The chromaticity coordinates (x=0.61, y=0.39) of the phosphors further validated the orange–red emission of the material. This phosphor may be used as near ultraviolet (n-UV) convertible orange–red emitting phosphor in light emitting diodes (LEDs).