Narrowband and Pure Violet Organic Emitter with a Full Width at Half Maximum of 14 nm and y Color Coordinate of Below 0.02.

Abstract

Violet organic light-emitting diodes (OLEDs) with a very narrow emission spectrum with a full width at half maximum of 14 nm and y color coordinate of 0.02 are developed using a indolo[3,2,1-jk]carbazole-derived pure violet emitter. The violet emitter, 2,5,13,16-tetra-tert-butylindolo[3,2,1-jk]-indolo[1',2',3':1,7]indolo[2,3-b]carbazole (tDIDCz), is designed to have a very rigid molecular structure driven by the multiresonance-type core structure through the alternating carbon and nitrogen atoms. The violet emitter is decorated with t-butyl groups to prevent intermolecular aggregation and packing, which allow pure violet emission without excimer emission. The violet OLEDs derived from the tDIDCz emitter show a violet color coordinate of (0.164, 0.018) with a narrow emission spectrum and a full width at half maximum of 14 nm (105 meV). The external quantum efficiency of the pure violet OLEDs is 3.3%. This is the first work reporting pure violet emission without any ultraviolet emission below 380 nm and blue emission above 450 nm by showing a very narrow emission spectrum.