Naphthyl-functionalized oligophenyls: Photophysical properties, film morphology, and amplified spontaneous emission

Abstract

Herein, we reported a series of deep-blue-emitting naphthyl-functionalized oligophenyls as new organic laser active materials with tunable wavelength from 385 to 410nm in solid state. Introduction of peripheral naphthyl into the oligophenyls enabled the great sterical dimensions due to the prominent steric hindrance but not destroyed the molecular conjugation. We assumed that it would suppress the π-π stacking efficiently, driving by intermolecular interaction, to hinder crystallization in solid films. Finally, the neat films of naphthyl-functionalized oligophenyls demonstrated amorphous state compared to the polycrystalline state of oligophenyls. Thus, naphthyl-functionalized oligophenyls displayed high emission quantum yield (22–35%) in solid state neat films. In addition, these molecules possessed large oscillator strength and radiative decay rate, as predicted by the theoretical analysis. The outstanding photophysical properties and amorphous films render naphthyl-functionalized oligophenyls a new class of optical gain media in solid state.