Naphthenic Acid Corrosion Mitigation: The Role of Niobium in Low-Carbon Steel

Abstract

Naphthenic acid corrosion is a well-recognized factor contributing to corrosion in the construction of offshore industry pipelines. To mitigate the corrosive effects, minor quantities of alloying elements are introduced into the steel. This research specifically explores the corrosion effects arising from immersing low-carbon steel, specifically A333 Grade 6, in a naphthenic acid solution. Various weight percentages of niobium were incorporated, and the resulting properties were observed. It was noted that the addition of 2% niobium in low-carbon steel exhibited the least mass loss and a lower corrosion rate after a 12 h immersion in naphthenic acid. Microstructural analysis using scanning electron microscopy (SEM) revealed small white particles, indicating the presence of oil sediment residue, along with corrosion pits. Following the addition of 2% niobium, the occurrence of corrosion pits markedly decreased, and only minor voids were observed. Additionally, the chemical composition analysis using energy-dispersive X-Ray analysis (EDX) showed that the black spot exhibited the highest percentage of carbon, resembling high corrosion attack. Meanwhile, the whitish regions with low carbon content indicated the lowest corrosion attack. The results demonstrated that the addition of 2% niobium yielded optimal properties for justifying corrosion effects. Therefore, low-carbon steel with a 2% niobium addition can be regarded as a superior corrosion-resistant material for offshore platform pipeline applications.