Abstract

In the title salt, [Co(C10H6O2)(C18H18N4)](C24H20B)·C3H6O·0.5H2O, the CoIII ion in the complex cation is six-coordinated in a rigid octa­hedral N4O2 geometry. The asymmetric unit contains one complete [Co(C10H6O2)(C18H18N4)]+ unit, one tetraphenylborate counter-anion and one acetone and one water mol­ecule that is located on an inversion centre. All the features of the CoIII ion are fully consistent with the formulation of the cation as a Co3+–catecholate complex. Variable-temperature magnetic measurements in the region 2–380 K show a obvious diamagnetism over the observed temperature range.

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